The electrochemical performance of lithium-oxygen batteries can be significantly improved by employing a suitable catalyst to enhance the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Herein, a versatile, effective and economic co-precipitation synthesis of spinel NiCo 2 O 4 with an urchin-like structure has been reported as an electrocatalyst for rechargeable non-aqueous Li-O 2 batteries. The spherical urchin-like structure of spinel NiCo 2 O 4 was formed without the use of any template or surfactant. The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) kinetics in the Li-O 2 batteries could be drastically improved by employing the effective NiCo 2 O 4 catalyst, achieving a higher discharge potential and rate. In particular, the urchin-like structure of the catalyst not only provides more electrocatalytic sites but also promotes mass transport in the electrolyte. In addition, mesoporous NiCo 2 O 4 can efficiently catalyze the formation and decomposition of Li 2 O 2 . The Li-O 2 battery containing the urchin-like NiCo 2 O 4 catalyst exhibited the highest specific capacity of about 7309 mA h g −1 at 0.2 mA cm −2 . The integrity and porosity of spinel NiCo 2 O 4 had a significant effect on the performance of the Li-O 2 battery with reasonable specific capacity and cyclability, suggesting that the NiCo 2 O 4 -based materials can be effective catalysts for oxygen electrode in high performance Li-O 2 batteries.Recently, Li-ion batteries (LIBs) have been the main energy storage media for portable electronic devices and electric vehicles/hybrid electric vehicles (EV/HEV). Unfortunately, the current LIBs can store only a limited amount of energy and are still relatively expensive. 1,2 In particular, to overcome the disadvantage of the insufficient energy density of LIB, a new battery chemistry with a higher energy density is needed. Recently, lithium-oxygen (Li-O 2 ) batteries have attracted much attention as a promising alternative to LIB for next generation electric vehicles, owing to their large theoretical energy density. 1,3-6 Among various types of Li-O 2 batteries, the non-aqueous system has achieved more encouraging results than other counterparts. 7,8 However, the stability and rate capability of the Li-O 2 battery need to be improved further for its commercialization. 5,9 The typical Li-O 2 cell consists of a porous oxygen electrode for the permeation of oxygen, an electrolyte containing a dissolved lithium salt, and a lithium metal electrode, which can greatly affect the capacity and durability of the cell. 10,11 In particular, the oxygen electrode and lithium electrode plays a crucial role in achieving high capacity and durability for the Li-O 2 battery and represent most serious challenge for the development of the battery. 6,12 Moreover, the large overpotential of the Li-O 2 battery is mainly attributed to the sluggish kinetics of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on the oxygen electrode. In addition, the rechargeability of the ...