There is limited research about the
formation of zeolite LTN under
Bayer process pre-desilication conditions. Here, we report on the
effect of alkaline (2–8 M NaOH) and aluminate concentrations
(0.125–0.75 M) using 0.1 or 0.2 M soluble silicate with respect
to its effect on zeolite crystallization within a pre-desilication
time range of 4 h. Whether the LTA or LTN phase forms first is found
to depend on both the aluminate and alkaline concentrations. With
a 2 M NaOH initial concentration, only an amorphous-to-LTA-phase transformation
is observed. For 4 and 6 M NaOH, decreasing the aluminate concentration
increases the proportion of the LTN phase compared to that of LTA.
The phase transformation between LTA and LTN was also observed. However,
only LTN transformed into SOD at 8 M NaOH. Select pure phases obtained
from the experiments were characterized by NMR and thermal gravimetry.
Amorphous, LTA, and LTN phases transformed into a low-carnegieite
phase, while SOD remained unchanged when heated to 850 °C. These
findings on zeolite LTN provide information on the further development
of the previously proposed Bayer sandy desilication product process.