Influence of Cu insertion on the thermoelectric properties of the quaternary cluster compounds Cu3M2Mo15Se19 (M = In, K) and Cu4In2Mo15Se19

Gougeon, P.; Gall, Philippe; Misra, Shantanu; Léon, Adèle; Gendarme, Christine; Migot, Sylvie; Ghanbaja, Jaâfar; Oualid, Soufiane El; Lenoir, Bertrand; Candolfi, Christophe

doi:10.1039/d3tc00214d

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Cited by 2 publications

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Carrier and morphologically tailored thermoelectric properties of MBi2O4 (M=Cu, Ni, and Zn) kusachiites

Aishwarya,

Navamathavan

2023

Surfaces and Interfaces

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Carrier and morphologically tailored thermoelectric properties of MBi2O4 (M=Cu, Ni, and Zn) kusachiites

Aishwarya,

Navamathavan

2023

Surfaces and Interfaces

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Calculating and analyzing the relationship between thermal conductivity and microstructure in rare-earth doped fluoride crystals

Liu,

Jiang,

Bian

et al. 2024

Preprint

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Rare earth (RE) ion-doped fluoride crystals have shown great application potential in various fields, attracting the attention of many researchers. The abnormal thermal transformation behavior of RE ion-doped fluoride crystals leads to the singularity and weakness of their application fields. Here, the influence of different structural characteristics of RE ion-doped fluoride crystals on the variation of thermal conductivity is further analyzed using phonon scattering calculation. Firstly, based on the effect of the phonon scattering mechanism on the thermal conductivity of RE ion-doped fluoride, a comprehensive analysis examines the diverse factors that affect the abnormal thermal behavior of different doping types and fluoride crystals. The actual thermal conductivity characteristics are predicted to optimize the crystal performance in various application fields of RE ion-doped fluoride crystals. Next, the influence mechanism of mass and radius difference caused by RE ion doping structure on the thermal conductivity of RE ion-doped fluorides is deeply investigated. Ultimately, a theoretical foundation for behavior and influence of disorder crystals' thermal conductivity is established.

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Influence of Cu insertion on the thermoelectric properties of the quaternary cluster compounds Cu₃M₂Mo₁₅Se₁₉ (M = In, K) and Cu₄In₂Mo₁₅Se₁₉

Abstract: Mo-based cluster compounds form a large class of materials with interesting thermoelectric properties primarily due to their very low lattice thermal conductivity. Here, we investigate the influence of the insertion...

Cited by 2 publications

References 75 publications

Carrier and morphologically tailored thermoelectric properties of MBi2O4 (M=Cu, Ni, and Zn) kusachiites

Carrier and morphologically tailored thermoelectric properties of MBi2O4 (M=Cu, Ni, and Zn) kusachiites

Calculating and analyzing the relationship between thermal conductivity and microstructure in rare-earth doped fluoride crystals

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