TiO2 film has the advantage of good photochemical stability and it can be
used for self-cleaning glasses. However, due to the wide band gap, the
spectral response range of TiO2 film is restricted to the ultraviolet
region. In this work, based on the research of TiO2 thin films, multilayer
TiN/Ag/Cu2O/TiO2 films were designed and successfully prepared. The
structure and properties of the obtained samples were characterized by X-ray
diffraction, spectral ellipsometry (SE), atomic force microscopy (AFM) and
UV-Vis-NIR spectrophotometer. The results show that p-n heterojunction will
be formed between Cu2O and TiO2 in the multilayer film, thus reducing the
band gap of TiO2 film. Based on the analysis of the photocatalytic mechanism
of the multilayer films, a conclusion may be drawn that the designed
multilayer film is helpful to improve the photocatalytic efficiency of
titanium dioxide and expand its utilization of sunlight.