Dissociation of CO 2 is investigated in an atmospheric pressure dielectric barrier discharge (DBD) with a simple, zero dimensional (0-D) chemical model and through experiment. The model predicts that the primary CO 2 dissociation pathway within a DBD is electron impact dissociation and electron-vibrational excitation. The relaxation kinetics following dissociation are dominated by atomic oxygen chemistry. The experiments included investigating the energy efficiencies and dissociation rates of CO 2 within a planar DBD, while the gas flow rate, voltage, gas composition, driving frequency, catalyst, and pulse modes were varied. Some of the VADER results include a maximum CO 2 dissociation energy efficiency of 2.5 ± 0.5%, a maximum CO 6 2 dissociation rate of 4 ± 0.4 ×10 − mol CO 2 /s (5 ± 0.5% percent dissociation), discovering that a resonant driving frequency of ∼30 kHz, dependent on both applied voltage and breakdown voltage, is best for efficient CO 2 dissociation and that TiO 2 , a photocatalyst, improved dissociation efficiencies by an average of 18% at driving frequencies above 5 kHz.