Jarosite (JS) is a zinc industry byproduct generated during the smelting process of zinc ore. Due to its high concentration of heavy metal ions, it has been declared a hazardous material by the United States Environmental Protection Agency. As a result, the utilization of JS is highly limited. Hence, geopolymer concrete provides an eco-friendly solution for producing sustainable concrete by incorporating various industrial byproducts. This study focuses on formulating a binary blended geopolymer concrete that incorporates ground granulated blast furnace slag (GGBS) and JS as precursor materials, which are activated using an alkali solution. The mix design for the GGBS-JS-based geopolymer concrete involves varying several parameters, including the proportion of JS, total aggregate percentages, alkali-to-binder ratios, and sodium hydroxide molarities. A total of 48 mix proportions of geopolymer concrete are prepared and investigated to determine the fresh and strength characteristics. Based on the experimental values, it is observed that the utilization of JS in geopolymer concrete elevates the dispersion of binders, which increases the workability of concrete by 44.5%, and a 47.37% reduction in compressive strength is observed as the JS incorporation is increased. With the collected experimental values, a new mix design procedure is proposed. Furthermore, selected concrete samples with varying JS percentages are studied to determine microstructural characteristics such as X-ray diffraction, scanning electron microscope, and fourier transform infrared spectroscopy to analyze the developed geopolymer concrete's phase transformation, surface morphology, and bond formation. This study also assessed JS's heavy metal leaching properties and observed that toxicity by leaching is reduced by up to 99%, which justifies the utilization of JS in geopolymer concrete as a sustainable solution for the zinc industry waste management system.