Influence of Film Thickness and Heat Treatment on the Physical Properties of Mn Doped Sb₂Se₃ Nanocrystalline Thin Films

Abstract

Nanocrystalline thin films of Sb37.07Mn1.95Se60.98 with different thickness (7, 20, 40, and 80 nm) were successfully prepared via inert gas condensation technique. As-deposited films showed amorphous structure by grazing incident in-plane X-ray diffraction (GIIXD) technique. All films of different thicknesses were heat treated at 433 K for 90 min. The GIIXD pattern of annealed films showed nanocrystalline orthorhombic structure. The effect of thickness of annealed films on the structure and optical properties was studied. Calculated particle sizes are 20.67 and 24.15 for 40 and 80 nm thickness of heat treated film. High resolution transmission electron microscope HRTEM images and their diffraction patterns proved that 40 nm film thickness annealed at different temperature has nanocrystalline nature with observed (high) crystallinity that increases with annealing temperature. Blue shift of optical energy gap was observed from 1.68 to 2 eV with decreasing film thickness from 80 to 7 nm. Film thickness of 40 nm was exposed to different heat treated temperatures from 353 to 473 K to detect its effect on structure and optical and electrical properties. Blue shift from 1.73 to 1.9 eV was observed in its optical band gap due to direct transition as heat treatment temperature decreasing from 473 to 353 K. Electrical conductivity was studied for different heat treated films of thickness 40 nm, and intrinsic conduction mechanism is dominant. The activation energy Ea was affected by heat treatment process.

The physical and optical properties of AZO thin films on teflon substrate at low deposition temperature by spray pyrolysis

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Solid-state Dewetting Formation of In/InTe Nanosystem

“…During SSD-induced self-assembling, the smaller deposited particles of indium desorb more atoms than larger ones, which stops the growth of nanostructures from particles smaller than a certain critical radius. There are a number of studies on the influence of the degree of surface coverage of the template on the morphology of nanostructures obtained on the surface [19][20][21][22]. We were able to establish an exponential dependence of the kinetics of the increase in the periodicity of nanostructures formed on the template surface via the degree of indium deposited coverage followed by the SSD process.…”

ZnO Multilayer Thin Films as The Seed Layer for ZnO Nanorods: Morphology, Structural and Optical properties

“…In addition, this grain size will increase if the thickness or chemical composition increases. These two factors will directly change the material (thin film) band gap (El Zawawi et al, 2017). Therefore, even though the same material was used, the optical energy band gap would change significantly with thickness and chemical composition changes.…”