Influence of Fuel Ash Characteristics on the Release of Potassium, Chlorine, and Sulfur from Biomass Fuels under Steam-Fluidized Bed Gasification Conditions

Abstract

Steam-fluidized bed gasification of biomass, which produces combustible gases from which transportation fuels can be synthesized, is a promising option for replacing the use of fossil fuels in the transportation sector. Similar to other thermal conversion processes, the release of potassium (K), chlorine (Cl), and sulfur (S) from biomass fuels to the gas phase during this process may be conducive to ash-related problems. Catalytic tar and char conversion by K has also been observed. In addition to operational conditions, the extent to which these elements are released to the gas phase may be affected by fuel ash characteristics such as the ash composition and the speciation (or association) of ash-forming elements in the fuel matrix. In the present work, the influence of these fuel ash characteristics on the extent to which K, Cl, and S are released from biomass fuels to the gas phase was studied under steam-fluidized bed gasification. The aim was to assess whether these fuel ash characteristics provide information that could be useful in making a quick judgment as to what extent K, Cl, and S would be released to the gas phase. To this end, the release of K, Cl, and S from forest residues and wheat straw during devolatilization and steam gasification of the char was quantified in a laboratory-scale bubbling fluidized bed reactor. The speciation of these elements in the virgin fuels was studied with chemical fractionation. The results reveal that the extent to which S is released from biomass fuels to the gas phase mainly depends on its speciation in the fuel matrix. While both the ash composition (mainly the Cl/K molar ratio) of the fuel and the speciation of K in the fuel matrix are relevant for the release of K, they appear to be unimportant with respect to the release of Cl.

Experimental study of potassium release during biomass-pellet combustion and its interaction with inhibitive additives

“…In order to obtain the potassium proportion in solid residues, inductively coupled plasma-optical emission spectrometry (ICP-OES) is usually employed [21] to measure the remaining elemental potassium. Very recently, Liu et al [22] used ICP-OES to investigate the effects of atmosphere and chlorine on potassium release during biomass combustion in a fluidized bed and the results show that the release proportion of potassium in air atmosphere was bigger than oxy-fuel environment and the overall activation energy for potassium release under air atmosphere is less than that under oxy-fuel atmosphere.…”

Release of potassium in association with structural evolution during biomass combustion

“…Most of the free potassium in living biomass is presented in the form of ions (K + ) in solution within the xylem cells [25]. During the air-drying process, these ions precipitate as inorganic K salts [26], which make up to 90% of the total K in raw biomass thermally stable at lower temperatures. The release of K and the mass loss of wheat straw samples as a function of temperatures is presented in Figure 2.…”

The use of gasification solid products as catalysts for tar reforming

“…With regards to the chemical composition, Fig. 3 presents a scheme of the species commonly found in different biomass ashes [ 31,32,43,47,54,68,[70][71][72][73][74]; from the values in the figure, it can be inferred that the most prevalent inorganic elements in the ashes are Si and Ca. Moreover, it is clear that the inorganic species come in different amounts from different biomasses.…”

“…3. Average fractions of inorganic species in a range of biomass ashes by type of biomass [31,32,43,47,54,[70][71][72][73][74]. Fig.…”