This work presents accurate ab initio investigations of various spectroscopic properties of a fewLi-like ions in presence of a plasma environment within the Debye screening potential. The coupledcluster theory in the relativistic framework has been employed to compute ionization potentials, excitation energies, electric dipole oscillator strengths, and electric quadrupole transition probabilities of Li-like C 3+ , N 4+ , and O 5+ ions. The unretarded Breit interaction has been implemented to increase the accuracy of the calculations. The effects of ion density and temperature on the ionization potentials, excitation energies, electric dipole oscillator strengths, and electric quadrupole transition probabilities have been investigated in the plasma environment. It is found that the plasma screening leads to a sharp decrease in the ionization potential as the screening strength increases. With increasing strength, the oscillator strengths associated with 2s 2 S 1/2 →2p 2 P 1/2,3/2 transitions increase, whereas the transition probabilities associated with 3d 2 D 3/2,5/2 →2s 2 S 1/2 transitions decrease.With the advent of novel x-ray sources based on free-electron lasers (FELs) [1, 2], laser plasmas [3], and high-harmonic generations [4,5], it is possible to achieve extreme conditions in matter such as high energy density and high temperature using ultraintense, ultrashort, and tunable pulses, and hence it is possible to create matter in plasma form [6,7]. There have been many experimental [6][7][8][9][10][11][12][13][14][15][16] and theoretical [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35] endeavors to explain and understand the effect of plasma environment on the spectroscopic properties of atoms and ions. In the situation, when atoms or ions embedded in plasma, the interaction between the nucleus and the bound electrons is screened by the surrounding ions and fast electrons. The modified interaction gives rise to phenomena such as pressure ionization and continuum lowering and affects the spectroscopic properties of atoms and ions [36,37]. Recent advanced experiment, carried out using FEL and electron beam ion trap (EBIT), provides an unexpected low oscillator strength of electric dipole (E1) transition of Fe 16+ and raises the concern about the quality of the atomic wave functions used to model such spectral properties [38]. Therefore, treating the effect of plasma environment in atoms and ions along with an accurate treatment of electron-electron correlation and relativistic effects are nontrivial. The ratio of Coulomb energy to thermal energy determine the strength of coupling (Γ) in plasma. The low density and high temperature situation corresponds to weakly coupled plasma (Γ < 1), where the screening of the nuclear Coulomb interaction by free electrons in the plasma is guided by the Debye model [39,40].Lithium and lithium-like ions in plasma are a few of the most abundant ionic species for specific temperature and density attainable in the laboratory [41]. Various spectroscopic ...