An
experimental study was performed on pressure evolution and flame
propagation for CH4 and its blends with C2H6, C2H4, CO, and H2 over its
entire flammable range for systems with various concentrations (0.4–2.0
%) and initial temperatures (298–373 K) of closed-vessel deflagration.
The peak explosion pressure (P
max) and
the maximum pressure rise rate (dp/dt)max were observed and analyzed. In the outwardly spherically
propagating flame method, the unstretched laminar burning velocity
(U
l) was obtained from the flame radius
with time. Within the range of the experiments, the results show that P
max decreases linearly and that (dp/dt)max first increases and then decreases
with increasing initial temperature at a constant initial concentration.
When a gas mixture is added to a 9.5 % CH4–air mixture, P
max and (dp/dt)max exhibit decreasing trends at a constant initial temperature.
A nonlinear regression formula was obtained, and this formula can
be used to predict P
max at different temperatures
and concentrations. The kinetic model using two detailed mechanisms
(GRI-Mech 3.0, FFCM-1) is compared with the experimental results using
linear and nonlinear models of stretch extrapolation. The laminar
burning velocities (LBVs) measured by FFCM-1 are closer to the experimental
value than those measured by GRI-Mech 3.0. The U
l values of CH4 and its blends with C2H6, C2H4, CO, and H2 increase
with an increase in the initial temperature. Based on the analysis
of experimental values, the temperature exponent (α) is derived
to predict the LBVs of the mixture at an elevated temperature under
atmospheric pressure.