The substructures of pearlite and martensite in a water-quenched
Fe-1.4C (wt %) binary alloy were investigated via optical microscopy,
scanning electron microscopy and high-resolution transmission electron
microscopy. In the carbide layers of the quenched pearlite lamellae,
θ-Fe3C-type cementite particles and several novel
carbides were observed. According to electron diffraction patterns,
the crystal structure of twinned martensite could not be characterized
as a body-centered tetragonal crystal structure, which is commonly
assumed. Instead, the patterns suggested that the twinned martensite
could be considered to have a body-centered cubic α-Fe {112}⟨111⟩-type
twinning structure accompanied by a metastable ω-Fe phase (ultrafine
particles) at the twinning boundaries. Furthermore, high-resolution
lattice observations of twinned martensite substructures demonstrated
that ω-Fe phase particles could exist independently in regions
without twinning structures, indicating that they were not solely
caused by overlap at twinning boundaries; thus, this prior assumption
was challenged. The mechanism of the formation of new carbides in
quenched pearlite and the presence of the ω-Fe phase in the
regions without twinning could be reasonably explained by the autotempering
or detwinning of the twinned martensite.