Influence of Nucleophilic Reagents on the Reactions of Phosphorus Sulfides and Alkyl Homologues of Davy's Reagent With Alkyl Halides and Dialkyl Disulfides

Nizamov, I. S.; Sergeenk, Gul'nur G.; Matseevskii, Alexey V.; Батыева, Э. С.

doi:10.1080/10426509808045492

Cited by 4 publications

(1 citation statement)

References 15 publications

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“…Reaction of benzyl chloride with P 4 S 10 in the presence of K 2 CO 3 in acetonitrile (dry) at 60−70 °C for 2 h gave tribenzyltetrathiophosphate (PhCH 2 S) 3 PS. , …”

Section: Reactions Of P4s10mentioning

confidence: 99%

A Berzelius Reagent, Phosphorus Decasulfide (P₄S₁₀), in Organic Syntheses

2010

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Introduction 3419 2. Reactions of P 4 S 10 3421 2.1. Ketones 3421 2.2. Thionoesters, Dithioesters, Thionolactones, Dithiolactones, Thiolactones, and Dithiolethiones 3426 2.3. Amides and Lactams 3435 2.4. Imides 3448 2.5. Thiophenes 3451 2.6. Thiazolines, Thiazoles, and Thiazines 3454 2.7. Dithiazoles 3456 2.8. Thiadiazoles 3456 2.9. Imidazolines and Pyrimidines 3456 2.10. Alcohols 3458 2.11. PdO to PdS 3461 2.12. Reduction 3462 2.13. Nucleotides, Purines, and Pyrimidines 3463 2.14. Miscellaneous 3467 2.15. P 4 S 10 vs Lawesson's Reagent (LR) 3473 3. Conclusion 3473 4. Acknowledgments 3473 5. References 3473

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“…Reaction of benzyl chloride with P 4 S 10 in the presence of K 2 CO 3 in acetonitrile (dry) at 60−70 °C for 2 h gave tribenzyltetrathiophosphate (PhCH 2 S) 3 PS. , …”

Section: Reactions Of P4s10mentioning

confidence: 99%

A Berzelius Reagent, Phosphorus Decasulfide (P₄S₁₀), in Organic Syntheses

2010

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Synthesis of Tetrathiophosphates from White Phosphorus

Shi

Zhang

et al. 2023

Chin. J. Chem.

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Comprehensive SummaryA transition‐metal‐free one‐pot direct synthesis of tetrathiophosphates (R1S)2P(S)SR2 from white phosphorus (P4), through intermediate sodium alkyltetrathiophosphates (R1S)2P(S)SNa, is presented. In the presence of NaSH, various disulfides such as diaryl disulfidbges and dialkyl disulfides are easily coupled with P4 to give sodium alkyltetrathiophosphates (R1S)2P(S)SNa in almost quantitative yield, which react with alkyl halides in one pot to generate (R1S)2P(S)SR2. Furthermore, S‐(2‐cyanoethyl)‐substituted tetrathiophosphates (R1S)2P(S)SCH2CH2CN are successfully designed as a kind of tetrathiophosphorylation reagent to react with diaryl iodonium salts involving deprotection‐dealkylation process.

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