Influence of Pre-oxidation on Filamentary Carbon Deposition on 20Cr25Ni Stainless Steel

Abstract

The results of a pre-oxidation heat treatment at 930 °C in Ar/H 2 /H 2 O environments on a Si-bearing Nb-stabilised 20Cr25Ni austenitic steel are presented. The heat treatment was conducted under low pO 2 , achieved by the introduction of controlled amounts of moisture into the gas. The atmosphere promoted the formation of a continuous, dense, adherent, protective surface scale composed of Cr 2 O 3 and MnCr 2 O 4 with a thin Si-rich oxide at the oxide alloy interface. Samples with different oxide layer thicknesses were produced and further exposed at 700 °C, to a gas of nominal composition CO 2 /1%CO/1000 vpm C 2 H 4 for 4 h. This gas mixture has a carbon activity greater than unity and readily forms filamentary carbon on the nonpre-oxidised alloy. This is catalysed by nickel particles formed intrinsically from the alloy during the early stages of oxidation of the unprotected surface. The oxide layers produced, as a result of the pre-oxidation process, could suppress carbon deposition onto the alloy; a significant reduction in carbon deposit was noted with an oxide of 125 nm thickness, and no deposit was found on the sample with an oxide thickness of 380 nm. The depth of depletion of chromium from the alloy correlated with the thickness of the oxide formed during the pre-oxidation heat treatment, but the chromium concentration at the oxide/metal interface remained at ~ 15-16 wt% and considered to be sufficient to reform a protective layer in the event of mechanical damage to the original. No additional chromium depletion of the alloy occurred during the 4-h deposition stage.

Comparison of Growth Characteristics and Properties of CVD TiN and TiO2 Anti-Coking Coatings

“…The formation of cokes on metallic surfaces from thermal decomposition of hydrocarbon fuels pyrolysis is a major concern in the development of hypersonic aircraft, in which the fuel serves as not only the propellant, but also the ideal coolants to resolve the problem of thermal management by removing the waste heat from aircrafts with the physical and chemical heat sink (sensible heat-absorbing and cracking heat-absorbing) [1][2][3]. Not only that, coking and anti-coking have become the important subject of attention for many researchers at home and abroad, in the chemical, energy, environmental protection, aerospace, military, and other fields [4][5][6]. The formation of cokes is often accompanied by metal dusting, which is a serious form of carburization of Fe-, Ni-, and Co-base alloys.…”