Influence of Pressure on Product Composition and Hydrogen Consumption in Hydrotreating of Gas Oil and Rapeseed Oil Blends over a NiMo Catalyst

Abstract

This study describes the co-hydrotreating of mixtures of rapeseed oil (0–20 wt%) with a petroleum feedstock consisting of 90 wt% of straight run gas oil and 10 wt% of light cycle oil. The hydrotreating was carried out in a laboratory flow reactor using a sulfided NiMo/Al2O3 catalyst at a temperature of 345 °C, the pressure of 4.0 and 8.0 MPa, a weight hourly space velocity of 1.0 h−1 and hydrogen to feedstock ratio of 230 m3∙m−3. All the liquid products met the EU diesel fuel specifications for the sulfur content (<10 mg∙kg−1). The content of aromatics in the products was very low due to the high hydrogenation activity of the catalyst and the total conversion of the rapeseed oil into saturated hydrocarbons. The addition of a depressant did not affect the cold filter plugging point of the products. The larger content of n-C17 than n-C18 alkanes suggested that the hydrodecarboxylation and hydrodecarbonylation reactions were preferred over the hydrodeoxygenation of the rapeseed oil. The hydrogen consumption increased with increasing pressure and the hydrogen consumption for the rapeseed oil conversion was higher when compared to the hydrotreating of the petroleum feedstock.