Abstract. Radiative Electron Capture (REC) in 4 to 12MeV/u Ge31+---~H2 collisions has been studied using an X-ray/particle coincidence technique. This technique allowed a systematic investigation of K-shell REC as well as a separation of REC into the projectile L-and Mshells. The cross sections are discussed within a general scaling picture based on the reduced projecti!e velocity. PACS: 34.70. + e When a highly charged ion interacts with a neutral target atom several recombination processes are possible. Radiative Electron Capture (REC) is a recombination phenomenon in which the highly charged ion captures a target electron and emits a photon. REC of free electrons, considered as a time reversed photoeffect, has been known for a long time [1]. However, it was not until 1972 that REC of bound, quasi-free target electrons was observed [2] and studied intensively, both experimentally and theoretically [3][4][5][6][7][8][9][10][11][12][13][14][15]. Within the impulse approximation quasi-free electrons can be treated as free as long as the binding energy in the target atom can be neglected with respect to the kinetic electron energy seen in the projectile frame. Detailed knowledge of the REC process is important for an understanding of ionic states in solid matter [12,16,17], tbr a description of capture processes in high energy collisions [15"], for modelling of electron cooling processes in storage rings [18], and the estimations of lifetimes of highly charged stored ions. Very recently, the application of REC for structure studies of heavy few-electron ions has been proposed as well [19].In this letter we report on the first systematic case studies for K-, L-, and M-REC observed in collisions of highly charged, decelerated heavy ions (Ge 31 +) with a H2 gas target in the energy range 4.5 to 11.5 MeV/u. It should be noted that the simultaneous detection of all three processes in one collision system is very difficult * Supported by KBN, Poland; Grant No. 201779101 due to background in the X-ray spectra produced by inner-shell excitation or ionization, non-radiative electron capture into projectile excited states, and electron bremsstrahlung. Therefore, in order to reduce the background from competing processes, coincidences between X-Rays and projectiles which captured one electron were registered in our experiment. To date, simultaneous observation of K-, L-, and M-REC was only possible for channeling conditions at energies similar to those used in our experiment [12]. In this case small impact-parameter processes like K-shell excitation and non-radiative capture were strongly reduced.The hydrogenic Ge 3t+ projectiles, at the energies mentioned above, were produced at the UNILAC facility of GSI Darmstadt by stripping in a C foil at 11.5 MeV/u and by subsequent deceleration down to the appropriate energies [20]. The charge state analyzed beam was collimated and directed into the collision area which consisted of an open, triply differentially pumped gas target. The central part of the target of 7.5 mm length was ob...