Epoxy composite coatings filled with boron nitride of single layer (SBN) were prepared through a dip-coating method. The friction and wear behaviors of the coatings were performed, and the results showed that the wear life of composite coatings was obviously higher than that of pristine coating with low SBN content; however, friction coefficients only decreased slightly. The optimal content of SBN was 3 wt.%, and the wear life of the composite coating increased by 179% compared with that of pristine coating. The morphology of worn surfaces was studied, and the wear mechanisms were discussed.