Alternating pyrolytic carbon/boron nitride (PyC/BN) n multilayer coatings were applied to the KD-II silicon carbide (SiC) fibres by chemical vapour deposition technique to fabricate continuous SiC fibre-reinforced SiC matrix (SiC f /SiC) composites with improved flexural strength and fracture toughness. Three-dimensional SiC f /SiC composites with different interfaces were fabricated by polymer infiltration and pyrolysis process. The microstructure of the coating was characterised by scanning electron microscopy, X-photoelectron spectroscopy and transmission electron microscopy. The interfacial shear strength was determined by the single-fibre push-out test. Single-edge notched beam (SENB) test and three-point bending test were used to evaluate the influence of multilayer interfaces on the mechanical properties of SiC f /SiC composites. The results indicated that the (PyC/BN) n multilayer interface led to optimum flexural strength and fracture toughness of 566.0 MPa and 21.5 MPa m 1/2 , respectively, thus the fracture toughness of the composites was significantly improved.