Influence of Slag Chemistry on the Dissolution of FeCr&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;4&lt;/sub&gt; in CaO–SiO&lt;sub&gt;2&lt;/sub&gt;–Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;–MgO Slag with Graphite Crucible

The present study provides fundamental information on the resource recyclability of the interconnect assembly, i.e., the steel interconnector and the nickel meshes, from an end-of-life JÜLICH Solid Oxide Cell Stack—F10 design. The interconnector is composed of iron, chromium, and less than 4 wt.% of other alloying elements, mainly cobalt and manganese. Calculated blended compositions with the nickel meshes revealed their potential as a raw material in the production of 4xx, 2xx, or 3xx stainless steels. The melting behavior of the interconnect assembly was investigated under different conditions, i.e., in inert and oxidizing atmospheres, with and without the addition of slag-forming fluxes. The results demonstrated preferential oxidation of chromium in a trivalent state within the stable cubic spinel phase. Finally, the experimental results were compared with the thermodynamic equilibrium calculations based on the available databases (FToxid, SGTE, and SGPS) in FactSage 8.1 software. The calculated tendency to oxidize is in the order of Cr > Mn > Fe > Co > Ni at P(O2) greater than 10−10 bar, validating the experimental results.

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Influence of Slag Chemistry on the Dissolution of FeCr<sub>2</sub>O<sub>4</sub> in CaO–SiO<sub>2</sub>–Al<sub>2</sub>O<sub>3</sub>–MgO Slag with Graphite Crucible

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References 34 publications

A novel strategy for recovery of heavy metals and synthesis of Co-rich alloy from the alkali-treated tungsten residue using photovoltaic silicon kerf waste

A novel strategy for recovery of heavy metals and synthesis of Co-rich alloy from the alkali-treated tungsten residue using photovoltaic silicon kerf waste

Unlocking the Value of End-of-Life JÜLICH Solid Oxide Cell Stack Interconnect Assembly: A Combined Experimental and Thermodynamic Study on Metallic Resource Recyclability

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