Abstract. Geopolymer coatings were coated on glass fibre-reinforced epoxy (GRE) pipe by using kaolin, white clay and silica sand as source materials and sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as alkaline solution. The microstructure and mechanical property of geopolymer coating on GRE pipe were methodically investigated through morphology analysis, and flexural strength test. The result indicates the microstructure and interfacial layer between geopolymer coating and GRE pipe significantly influence the mechanical property of geopolymer coating. However, different source materials gave different microstructure and property in geopolymer coating.