2010
DOI: 10.1007/s11172-010-0137-9
|View full text |Cite
|
Sign up to set email alerts
|

Influence of structural factors on the thermolysis of 2-alkoxytetrafluoropropionic acid salts

Abstract: 2,2,2 Trifluoroethyl and phenyl trifluorovinyl ethers were obtained by the thermolysis of 2 substituted potassium tetrafluoropropionates ROCF(CF 3 )COOK (R = CF 3 CH 2 ; Ph). The reaction mechanism is analyzed.Key words: hexafluoropropylene oxide, 2 alkoxytetrafluoropropionic acids, 2 phenoxy tetrafluoropropionic acid, alkyl trifluorovinyl ethers, phenyl trifluorovinyl ether.Thermal decomposition of fluorocarboxylic acids is a universal method for the synthesis of higher linear fluo roolefins. 1,2 A particular… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4

Citation Types

0
7
0

Year Published

2014
2014
2020
2020

Publication Types

Select...
2
1

Relationship

0
3

Authors

Journals

citations
Cited by 3 publications
(7 citation statements)
references
References 7 publications
0
7
0
Order By: Relevance
“…5 in the manuscript gives 70 °C/60 mmHg) yielded 7.42 g, 83% of pentafluorosulfanyldifluoroacetic acid. 1 H NMR (300 MHz, CDCl 3 ) δ 11.09 (s, 1 H). 19 F NMR (283 MHz, CDCl 3 ) δ 64.2 (n, J = 147 Hz, 1 F), 41.7 (dm, J = 147 Hz, 4 F), -92.3 (qn, J = 11 Hz, 2 F).…”
Section: Pentafluorosulfanyldifluoroacetic Acidmentioning
confidence: 99%
See 4 more Smart Citations
“…5 in the manuscript gives 70 °C/60 mmHg) yielded 7.42 g, 83% of pentafluorosulfanyldifluoroacetic acid. 1 H NMR (300 MHz, CDCl 3 ) δ 11.09 (s, 1 H). 19 F NMR (283 MHz, CDCl 3 ) δ 64.2 (n, J = 147 Hz, 1 F), 41.7 (dm, J = 147 Hz, 4 F), -92.3 (qn, J = 11 Hz, 2 F).…”
Section: Pentafluorosulfanyldifluoroacetic Acidmentioning
confidence: 99%
“…Removal of the solvent by distillation gave 0.164 g, 70% of compound 7d as a volatile oil. 1 H NMR (300 MHz, CDCl 3 ) δ 3.44 (q, J = 6 Hz, 2 H), 3.41 (q, J = 6 Hz, 2 H), 1.22 (t, J = 6 Hz, 3 H), 1.13 (t, J = 7.2 Hz, 3 H). 19 F NMR (283 MHz, CDCl 3 ) δ 67.2 (n, J = 148 Hz, 1 F), 40.7 (dm, J = 148 Hz, 4 F), -84.2 (qn, J = 11 Hz, 2 F).…”
Section: Pentafluorosulfanyldifluoroacetic Acidmentioning
confidence: 99%
See 3 more Smart Citations