Influence of Submicron TiO₂ Particles on the Mechanical Properties and Fracture Characteristics of Cured Epoxy Resin

Abstract

Submicron titanium dioxide (TiO 2 ) was used in different weight fractions as a toughening agent for amine-cured epoxy resin. After the use of X-ray photoelectron spectroscopy (XPS), which confirmed that the TiO 2 particles were evenly distributed in the cross-linked epoxy resin matrix, the composites were characterized by tensile and impact testing, followed by scanning electron microscopy of the fracture surfaces. The results indicated that the submicron TiO 2 toughening particles markedly improved the mechanical properties of the cured epoxy resin compared to the untoughened epoxy resin. The optimal properties were achieved at a TiO 2 concentration of 4 wt. %, at which point the toughness and the impact resistance values increased by 65% and 60%, respectively. The results also indicated that an increase in the amount of TiO 2 causes a decrease in toughness. Stress whitening, out-of-plane flaking, and thumbnail markings were the major visible features of the toughening mechanisms.It is suggested that, at 4 wt. % of the submicron TiO 2 particles, microvoids are developed in the epoxy matrix. These microvoids are able to absorb some of the deformation work applied to the material, and thus enhance the toughness of the material. On increasing the TiO 2 content in the matrix ( > 4 wt. %), the submicron particles got closer to each other and the microvoids were converted to macrovoids, which may act as stress concentrating flaws, leading to the deterioration of the mechanical properties of the epoxy resin.

A Study on Thermal, Mechanical and Electrical Properties as Silane Treated Epoxy/MICA Composites

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