The production of cast iron in the USSR is increasing because of the construction of large blast furnaces and faster worMng of the blast by oxygen enrichment in combination with carbon-and hydrogen-containing additives, raising the temperature of the blow, the pressure, improving the quality of the batch, etc. The increased stability of conditions has increased the demands for better refractories. The problem of the next five-year plan is to increase the average resistance of the shift refractories to 9-10 years, and in the bosh and hearth to 18-20 years [1]. On the basis of a study of the operation of refractories in the blast furnace structure and postserviee studies it was established that the resistance depends on a combination of many critical factors [2][3][4][5][6][7][8].Each hour hundreds of kilograms of alkalis separate from the furnace blast with the ascending gases. Some of this is taken up by the lining, influencing the behavior of zinc, zinc compounds, and carbon, and altering to a significant extent the physieomechanical properties of the refractory and its phase composition. The alkaline compounds (oxides, carbonates, chlorides, sulfates, sulfides, etc.) above 800~ begin to react, in the gaseous state within a neutral or oxidizing atmosphere, with the chamotte refractories to form alkaline aluminosilicates.After service in the shaft the refractories are dark in color due to the saturation of dispersed carbon and are coated over their entire thickness with white scum from alkaline compounds. The refractoriness is much reduced after service, and in the main equals 1610-1370~ and below, depending on the degree of saturation by alkalis.