Influence of the processing parameters of slurries for the deposit of nickelate thick films

Castillo, S.; Cienfuegos, Rene Fabian; Fontaine, Marie‐Laure; Lenormand, Pascal; Bacchin, Patrice; Ansart, Florence

doi:10.1016/j.materresbull.2007.01.011

Cited by 12 publications

(9 citation statements)

References 11 publications

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“…The rather poor cell performance reported in literature usually comes from the high resistance of cathode-electrolyte interface that is probably due to the preparation process. In order to deposit a cathode layer on the smooth ceramic surface, high viscosity slurry or sol is usually applied to coating on electrolyte surface by screenprinting [1,2], paste brushing [3], dip-coating [4,5] and painting [6]. Spraying process such as electrostatic spraying [7], plasma * Corresponding author.…”

Section: Introductionmentioning

confidence: 99%

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

Dong

Liu

Xie

et al. 2008

Journal of Power Sources

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Section: Introductionmentioning

confidence: 99%

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

Dong

Liu

Xie

et al. 2008

Journal of Power Sources

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“…This layer was prepared by a sol–gel‐modified process at CIRIMAT—Toulouse, France. More details on the preparation process can be found in Castillo and colleagues 31,32 A disk of polycrystalline YSZ was polished until its surface roughness ( R a ) was <10 nm. The surface was then cleaned by immersion in deionized water and dried in air before deposition.…”

Section: Methodsmentioning

confidence: 99%

High-Temperature Radiative Behavior of an La2NiO4+δ Cathodic Layer for SOFCs (up to 900°C): Influence of δ and Texture

Rousseau

Campo

et al. 2011

Journal of the American Ceramic Society

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Thermal radiation is likely to play an important role in the calculation of the energy balance in solid oxide fuel cells (SOFCs), due to their high operating temperatures (6001-10001C). However, the majority of previous studies dealing with this issue have used room-temperature radiative data for determining the overall heat transfer process within a given cell, which could lead to an inexact appreciation of the role played by the thermal radiation. Consequently, the thermal field within the cell could also be incorrectly determined; however, accurate knowledge of the thermal field is important in order to understand the mechanical behavior of SOFCs. Several parameters, including chemical composition, texture, thickness, and of course operating temperature, have a large effect on the radiative properties of a given compound. As a first step to elucidate the temperaturedependent behavior of SOFCs, we deposited an La 2 NiO 41d cathodic layer on a planar ZrO 2 -8% Y 2 O 3 electrolyte-supported SOFC and investigated its radiative properties using hightemperature infrared emissivity spectroscopy (1001-9001C). Additional X-ray diffraction, thermo-gravimetric analysis, and environmental scanning electron microscopy measurements were also made to study the role played by both the chemical composition and texture on the radiative properties of the cell. 30 J. Stevenson-contributing editor *Member, The American Ceramic Society.

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“…In this scheme, the cathode should consist of both electronic and ionic conductors MIEC (Mixed Ionic and Electronic Conductor), because the oxygen reduction takes place in the triple point of contact (TPB -Triple Phase Boundaries). The material was already synthesized with La 4 Ni 3 O 10 for the ratio 3 [2], but was not optimized.…”

Section: Principle Of a Sofcmentioning

confidence: 99%

“…Fuel cell devices convert chemical energy directly into electrical energy without direct combustion as intermediary step. This increases conversion efficiency when compared to conventional power generation combustion systems with the added benefit of low emissions of gases like CO 2 , NO x and SO x [1][2][3][4][5][6].…”

Section: Introductionmentioning

confidence: 99%

ELABORATION AND CHARACTERIZATION OF La₄Ni₃O₁₀ CATHODE MATERIAL (SOFC) BY SOL-GEL PROCESS

Cienfuegos¹,

Guerrero²,

Carranza³

et al. 2011

MRS Proc.

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The goal in this study was to synthesize a lanthanum -nickel phase (Ruddlesden-Popper phases) La 4 Ni 3 O 10 . This material was prepared using a polymeric route. An easy synthesis method is presented in order to obtain an economical cathode material, which can be used in Solid Oxide Fuel Cells (SOFC). The polymeric precursors were prepared following the Castillo method. The originality of this work was to optimize the ratio HMTA/ metallic salts from 1 to 6. The obtained powders were characterized by thermal analysis; Differential Scanning Calorimetry (DSC Q10 Instrument TA), Thermogravimetric Analysis (TGA -Q50 Instrument TA-) and Xray diffractometer (Bruker, D8 Advance diffractometer), in order to determine the crystallized phase. Experiments 5 and 6 did not present coagulation but after few days, solution 5 was transformed into a gel. Gels 2 to 5 were heated in order to obtain a solid material. These powders are characterized by thermogravimetric and thermo-differential methods. The powders obtained at 800, 900 and 1000°C were analyzed by X-ray diffraction and it was found that the temperature to get to the La 4 Ni 3 O 10 phase was 1000ºC.

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Influence of the processing parameters of slurries for the deposit of nickelate thick films

Cited by 12 publications

References 11 publications

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

High-Temperature Radiative Behavior of an La2NiO4+δ Cathodic Layer for SOFCs (up to 900°C): Influence of δ and Texture

ELABORATION AND CHARACTERIZATION OF La₄Ni₃O₁₀ CATHODE MATERIAL (SOFC) BY SOL-GEL PROCESS

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Influence of the processing parameters of slurries for the deposit of nickelate thick films

Cited by 12 publications

References 11 publications

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

Comparative study on the performance of tubular solid oxide fuel cells with various Pr0.35Nd0.35Sr0.3MnO3/YSZ cathode layers made by different processes

High-Temperature Radiative Behavior of an La2NiO4+δ Cathodic Layer for SOFCs (up to 900°C): Influence of δ and Texture

ELABORATION AND CHARACTERIZATION OF La4Ni3O10 CATHODE MATERIAL (SOFC) BY SOL-GEL PROCESS

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ELABORATION AND CHARACTERIZATION OF La₄Ni₃O₁₀ CATHODE MATERIAL (SOFC) BY SOL-GEL PROCESS