Influence of the rigidity of the steroid core in the structure of chiral dopants on the temperature dependence of cholesteric short pitch

Nature is highly efficient at producing chiral compounds that are enantiomerically pure. The inherent chirality of naturally occurring biomolecules means that many have the potential to be used as chiral dopants for cholesteric liquid crystal (CLC) systems. Though many biomolecules have been identified as chiral dopants, many remain yet to be probed for their ability to function as chiral dopants. Here, 10 naturally occurring biomolecules comprised of steroids and bile acids were tested as chiral dopants for CLCs. Progesterone was identified as having high miscibility with nematic liquid crystals and was used in responsive liquid crystal devices. Progesterone-doped CLC devices were fabricated to exhibit either normal mode or reverse mode switchable behavior. Polymer stabilized CLCs (PSCLC) devices exhibiting dynamic electro-optic red- and blue-tuning behaviors were also fabricated. Furthermore, immiscible lithocholic acid was synthetically modified to afford two derivatives that were miscible at 10 wt. % in nematic liquid crystals. The two lithocholic acid derivatives were used as chiral dopants and incorporated into polymer stabilized CLCs which exhibited blue tuning behavior.

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Influence of the rigidity of the steroid core in the structure of chiral dopants on the temperature dependence of cholesteric short pitch

Cited by 3 publications

References 29 publications

Synthesis and properties of side-chain liquid crystalline polymers grafted with chiral dimers containing cholesteryl groups

Synthesis and properties of side-chain liquid crystalline polymers grafted with chiral dimers containing cholesteryl groups

Liquid-crystalline dimers containing cholesteryl groups and azobenzene moieties with branched allyl chain: synthesis and properties

Investigating the Electro-Optic Response of Steroid Doped Liquid Crystal Devices

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