2023
DOI: 10.1002/app.54448
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Influence of the π‐bridge and heteroatom on fluorene‐based donor‐acceptor polymers: Structure and optoelectronic properties

Myllena S. Pereira,
Luis O. Araujo,
Mikaela Daros
et al.

Abstract: Conjugated copolymers possess intriguing electronic characteristics that can be precisely modulated by manipulating their chemical structures. In this study, we explored two approaches for fine‐tuning the energy levels of these copolymers: the incorporation of heterocyclic moieties between the donor and acceptor units, and the substitution of a chalcogen atom in the acceptor unit. Specifically, we investigated the insertion of a thiophene along the polymer backbone and the replacement of sulfur with selenium i… Show more

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