2008
DOI: 10.1016/j.jallcom.2006.10.071
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Influence of tin on the electrochemical and gas phase hydrogen sorption in Mg2−xSnxNi (x=0, 0.1, 0.3)

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Cited by 6 publications
(5 citation statements)
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References 21 publications
(28 reference statements)
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“…It can be concluded that the amount of absorbed hydrogen decreases immediately after the first cycle. Both alloys show comparable corrosion stability, substantially lower than that of pure Mg 2 Ni [26]. Although the alloy with lower B content reveals slightly better electrochemical hydrogen charge/discharge behavior compared to the B richer alloy the discharge capacity and cycle life as a whole are rather low and unsatisfactory.…”
Section: Electrochemical Hydriding/dehydridingmentioning
confidence: 92%
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“…It can be concluded that the amount of absorbed hydrogen decreases immediately after the first cycle. Both alloys show comparable corrosion stability, substantially lower than that of pure Mg 2 Ni [26]. Although the alloy with lower B content reveals slightly better electrochemical hydrogen charge/discharge behavior compared to the B richer alloy the discharge capacity and cycle life as a whole are rather low and unsatisfactory.…”
Section: Electrochemical Hydriding/dehydridingmentioning
confidence: 92%
“…7 for both alloys. The B containing Mg 2 Ni alloys show however worse electrochemical hydrogen storage properties in comparison with the pure intermetallic compound [26].…”
Section: Electrochemical Hydriding/dehydridingmentioning
confidence: 96%
“…Mechanical milling is a highly appropriate technique for producing amorphous and nanocrystalline Mg 2 Ni alloys with different compositions. Drenchev et al [13] synthesized Mg 2-x Sn x Ni (x = 0, 0.1, 0.3) alloys with the average grain sizes ranging from 3 to 7 nm by means of reactive ball milling. However, these compounds showed the highest discharge capacity of only about 300 mAh g -1 , which declined to below 50 mAh g -1 after five charging and discharging cycles.…”
Section: Introductionmentioning
confidence: 99%
“…It has a specific capacity about 300-320 mAh/g and is appreciably expensive as cobalt metal is contained. Now the research focus on two aspects: one is to develop hydrogen absorbing alloys with higher capacity and lower price, such as Mg-Ni alloy [1][2], the other is to lower the content of cobalt in AB 5 alloy [3][4]. But till now, these new alloys can hardly meet the requirements of industrial production because of their poor life performance.…”
Section: Introductionmentioning
confidence: 99%