Influence of Treated Distillate Aromatic Extract (TDAE) Content and Addition Time on Rubber-Filler Interactions in Silica Filled SBR/BR Blends

Abstract

High compatibility and good rubber–filler interactions are required in order to obtain high quality products. Rubber–filler and filler–filler interactions can be influenced by various material factors, such as the presence of processing aids. Although different processing aids, especially the plasticizers, and their effects on compatibility have been investigated in the literature, their influence on rubber–filler interactions in highly active filler reinforced mixtures is not explicit and has not been investigated in depth. For this purpose, the influence of treated distillate aromatic extract (TDAE) oil content and its addition time on interactions between silica and rubber chains were investigated in this study. Rubber–filler and filler–filler interactions of uncured and cured silica-filled SBR/BR blends were characterized by using rubber layer L concept and dynamic mechanical analysis, whereas mechanical properties were studied by tensile test and Shore A hardness. Five parts per hundred rubber (phr) TDAE addition at 0, 1.5, and 3 min of mixing were characterized to investigate the influence of TDAE addition time on rubber–filler interactions. It was observed that addition time of TDAE can influence the development of bounded rubber structure and the interfacial interactions, especially at short time of mixing, less than 5 min. Oil addition with silica at 1.5 min of mixing resulted in fast rubber layer development and a small reduction in storage shear modulus of uncured blends. The influence of oil content on rubber–filler and filler–filler interactions were investigated for the binary blends without oil, with 5 and 20 phr TDAE content. The addition of 5 phr oil resulted in a slight increase in rubber layer and 0.05 MPa reduction in Payne effect of uncured blends. The storage tensile modulus of vulcanizates at small strains decreased from 13.97 to 8.28 MPa after oil addition. Twenty parts per hundred rubber (phr) oil addition to binary blends caused rubber layer L to decrease from 0.45 to 0.42. The storage tensile modulus of the vulcanizates and its reduction with higher amplitudes were incontrovertibly high among the vulcanizates with lower oil content, which were 13.57 and 4.49 MPa, respectively. When any consequential change in mechanical properties of styrene–butadiene rubber (SBR)/butadiene rubber (BR) blends could not be observed at different TDAE addition time, increasing amount of oil in blends enhanced elongation at break, and decreased Shore A hardness and tensile strength.

Fatty acid modified cellulose: Preparation and application as green multi‐functional additive in a tyre tread formulation

“…Inter‐layer lubrication along with less viscous matrix may be attributed to this occurrence. Substitution of process oil by FAC has reduced inter molecular plasticization effect 25 …”

“…Substitution of process oil by FAC has reduced inter molecular plasticization effect. 25 Reduction in lubricity has instigated higher internal shear forces between chains and thus resulted in improved polymer-filler interaction in composites having FAC. 4 Exp.…”

Coordinated control study of oil, wax, and antioxidants on tire sidewall rubber discoloration and fatigue properties

“…When the aromatic oil exceeds 4 phr, the precipitation becomes basically unchanged. Toluene, xylene, and low-grade alkanes are the major constituents of environmentally beneficial aromatic oil, 44,45 and antioxidant N3100 is N-phenyl-N 0 -(2,6-dimethylphenyl) p-phenylenediamine. The similar chemical structure between the two components produced by the benzene ring leads to a strong interaction between their molecules or molecular chains.…”

Triethoxysilyl-Terminated Telechelic Liquid Butadiene Rubber with Disulfide Linkages for Tire Tread of Electric Vehicles

“…Among these components, processing aids are used to reduce the viscosity of the compound, thereby enhancing its processability . However, the most commonly used processing aid, treated distillate aromatic extracted (TDAE) oil, decreases the physical properties such as rolling resistance and abrasion resistance when incorporated into the compound. , Moreover, owing to its absence of chemical bonding with the base rubber or filler, oil migration can occur to the tire surface over time during driving and degradation of the tire performance. , …”