2017
DOI: 10.1016/j.gca.2016.10.018
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Influence of vacancy damage on He diffusion in apatite, investigated at atomic to mineralogical scales

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Cited by 71 publications
(69 citation statements)
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“…A consistent observation is that the younger AHe ages are better reproduced by the model, while the older ages are underpredicted. This is consistent with our current understanding on how radiation damages repair over time and temperature and interact at high densities [ Ketcham et al ., ; Gerin et al ., ]. Despite the discrepancy between the predicted and model AHe ages, the thermal histories produced are those that best fit the observed data, considering the given uncertainty ranges.…”
Section: Resultsmentioning
confidence: 98%
“…A consistent observation is that the younger AHe ages are better reproduced by the model, while the older ages are underpredicted. This is consistent with our current understanding on how radiation damages repair over time and temperature and interact at high densities [ Ketcham et al ., ; Gerin et al ., ]. Despite the discrepancy between the predicted and model AHe ages, the thermal histories produced are those that best fit the observed data, considering the given uncertainty ranges.…”
Section: Resultsmentioning
confidence: 98%
“…These contentions suggest that the possible effect of radiation damage on the AFT ages is unlikely and as such will not be explored further within this work. Single grain AHe ages from basement lithologies display high levels of age dispersion ranging between 4% and 225%. Dispersion of the AHe ages can be attributed to several possible factors; 4 He ejection (Farley, Wolf, & Silver, ), 4 He implantation (Spiegel, Kohn, Belton, Berner, & Gleadow, ), U‐ and Th‐rich mineral inclusions (Fitzgerald, Baldwin, Webb, & O'Sullivan, ; Vermeesch et al., ), zonation (Flowers & Kelley, ), fragmentation (Brown et al., ), grain size (Reiners & Farley, ) and radiation damage (Djimbi et al., ; Flowers et al., ; Gautheron et al., , ; Gerin et al., ; Shuster, Flowers, & Farley, ), all of which can augment the age and increase the level of age dispersion. In roughly half of the samples, AHe age exhibits a weak to moderate positive trend against eU, while only 4 of 28 samples exhibit a weak to moderate positive correlation between AHe age and equivalent radius (Figure and Data S1).…”
Section: Methodsmentioning
confidence: 99%
“…This comparison reveals that processes such as the creation of radiation damage‐induced traps significantly alter He diffusion in zircon. In addition, the impact of chemical substitution or single vacancies can be investigated using DFT (Djimbi et al, ; Gerin et al, ; Saadoune & De Leeuw, ). Thus, atomistic calculations of He diffusion in perfect crystal lattices identify parameters that alter diffusion, providing new perspectives when diffusion coefficient measurements are not available or difficult to perform.…”
Section: Advances In Thermochronometry Systematicsmentioning
confidence: 99%
“…Radiation damage impacts He diffusivity in apatite Gautheron et al, 2009;Gerin et al, 2017;Recanati et al, 2017;Shuster et al, 2006;Willett et al, 2017) 10.1029/2018TC005312 Tectonics Hurley, 1952;Reiners, 2005). Provided grains experience the same thermal history, the measured effective U concentration (eU, where eU is calculated as [U] + 0.234 * [Th] + 0.0046 * [Sm]; Gastil et al, 1967) corresponds to relative radiation damage.…”
Section: Radiation Damage and Chemistry Controls On (U-th)/he And Ft mentioning
confidence: 99%
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