With the widespread adoption of electronic technology, electromagnetic (EM) interference has become increasingly severe, adversely affecting the normal operation of electronic systems and posing significant threats to human health. EM shielding materials can effectively suppress various EM waves and EM interference generated through space by improving the EM compatibility of electronic systems and electronic devices. Recently, fiber-structure materials have been widely used for EM shielding due to their softness, thinness, and superior shielding efficiency. Therefore, this paper focused on fiber-based EM shielding materials, discussed the basic principles of EM shielding, the types of EM shielding fibers, the efficiency factors of EM shielding fabrics, and presented prospects for the future development of such materials.