SeO 2 glasses are potential candidates for the applications in electrical and magnetooptical sensors, in catalysis and in a variety of semiconductor devices. These are also good infrared (IR) transmitters [1-3] and are being extensively used in photonic and non-linear optical devices. However, selenium oxide is an incipient glass former. It takes part in the glass formation only in combination with modifiers and conventional glass formers, e.g., borate, phosphate, silicate, and so on. Interestingly, during glass forming, the Se ion's coordination number (CN) varies from 4 to 3. The ions with CN 3 form quarantined selenite [SeO 3 ] 2À units, act as modifiers, and introduce internal chaos in the glass network; [4] such deaugmentation of the network paves the way for the enhancement of luminescence efficiency of dopant rare-earth (RE) ions by inhibiting the phonon losses. In contrast, the Se ions with CN 4 form selenate [SeO 4 ] 2À groups and alternate with BO 4 units in the glass network. In selinte (SeO 3) structural groups, out of 4p-electrons of Se, two electrons (of 4p-orbitals) join with with O À ions through covalent bondings, whereas the third 4p-orbital contains lone pair of electrons. Electronic polarizability of this oxide is expected to