In this study, an attempt was made to investigate the pitting and intergranular corrosion susceptibility of as-deposited and thermally aged weldments of type 316LN stainless steel (SS) made by shielded metallic arc (SMA) welding process using 316 SS filler wires having a carbon content of 0.059 wt%. The delta-ferrite content, which was 4.5 FN (Ferrite Number) for the as-welded samples, changed to 0.3 FN after the aging treatment (1023 K/5 h). Initial deltaferrite on thermal aging decomposed to various secondary phases like sigma and M 23 C 6 and chi. These phases were confirmed metallographically and identified by the powder x-ray diffraction method. Pitting corrosion resistance was determined at ambient temperature in neutral chloride and acidic chloride media on both as-welded and thermally aged weld metal samples by anodic polarization technique. The results indicated that in neutral and acidic chloride media, the pitting corrosion resistance of thermally aged samples was lower compared to that of the as-welded samples. No intergranular corrosion was observed on both types of specimens when determined by ASTM (1) -A262 practice E and F tests and by EPR tests.KEY WORDS: austenitic stainless steel, critical pitting potential, delta-ferrite, intergranular corrosion, M 23 C 6 -sigma precipitation SCIENCE CORROSION-JULY 1992 attacked in the as-deposited weld metal whereas chromium-and molybdenum-depleted regions (discontinuous), present along the austenite/delta-ferrite (transformed) boundaries, were attacked in the case of thermally aged weld metal.
CONCLUSIONS❖ Thermal aging of type 316 SS weld metal (1023 K for 5 h) resulted in deterioration of its pitting resistance because of the transformation of delta-ferrite to M 23 C 6 , sigma, and chi phases. ❖ Both the as-deposited and thermally aged (1023 K/5 h) welds, containing 4.5 FN delta-ferrite and 0.3 FN delta-ferrite, respectively, showed no signs of sensitization when tested according to ASTM-A262 practice E or F or in EPR test.