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Aging of the relaxors and PbMg 1 / 3 Nb 2 / 3 O3 in particular was extensively studied in last two decades. Most of the results were related to the low temperature glass-like region. No systematic data around the freezing temperatures were reported. To cover this still missing information we have studied the evolution of the dielectric spectra in the broad frequency region from 10−1 Hz to 106 Hz both below and above the freezing temperature T f ≈ 240 K. Below freezing temperature the existence of the earlier reported waiting time–frequency scaling at frequencies below ≈50 Hz is confirmed. At higher frequencies this deviation from the scaling is observed that can be tentatively attributed to the complexity of the relaxing entities. Above Tf aging is observed only in the restricted frequency interval below the maximum of the dielectric loss spectrum. The observed effect can be attributed to the hardening and narrowing of the dielectric loss spectra and decreasing of the dielectric strength with time. The explanation is proposed based on the concept of the creation of the degenerate polar nanoregions covering several chemically ordered regions (COR) (multi PNRs—MPNRs). These MPNRs are large compare to the PNRs located at the single CORs and some of them may become frozen resulting in the described spectra changes.
Aging of the relaxors and PbMg 1 / 3 Nb 2 / 3 O3 in particular was extensively studied in last two decades. Most of the results were related to the low temperature glass-like region. No systematic data around the freezing temperatures were reported. To cover this still missing information we have studied the evolution of the dielectric spectra in the broad frequency region from 10−1 Hz to 106 Hz both below and above the freezing temperature T f ≈ 240 K. Below freezing temperature the existence of the earlier reported waiting time–frequency scaling at frequencies below ≈50 Hz is confirmed. At higher frequencies this deviation from the scaling is observed that can be tentatively attributed to the complexity of the relaxing entities. Above Tf aging is observed only in the restricted frequency interval below the maximum of the dielectric loss spectrum. The observed effect can be attributed to the hardening and narrowing of the dielectric loss spectra and decreasing of the dielectric strength with time. The explanation is proposed based on the concept of the creation of the degenerate polar nanoregions covering several chemically ordered regions (COR) (multi PNRs—MPNRs). These MPNRs are large compare to the PNRs located at the single CORs and some of them may become frozen resulting in the described spectra changes.
One of the key points in the physics of the relaxors is their response to the applied DC field. Many studies of this topic were made, in particular on the influence of the field on the dielectric properties. However, practically, in all the cases, the measurements were performed at a fixed frequency and usually with the change in the temperature at the fixed field strength. In this paper, we report the evolution of the dielectric spectra at low frequencies (0.1 Hz [Formula: see text] 1 kHz) at fixed temperature 246 K on changing the DC electric field applied in (111) from 1 kV to 7 kV. Cole-Cole function was used to describe the spectra and the field dependences of the mean relaxation time [Formula: see text], the oscillation strength [Formula: see text] and the width parameter [Formula: see text] were determined. The obtained [Formula: see text]([Formula: see text]) and [Formula: see text] [Formula: see text]([Formula: see text]) provide evidence of the field-induced transition from the nonpolar glass-like phase to the nonpolar paraelectric phase at around 1.5 kV/cm. In the paraelectric phase, very fast hardening of the spectra was observed with [Formula: see text] changing from 10 s to about 10[Formula: see text]s. The performed analysis demonstrated that the earlier reported positive C-V effect is completely determined by the spectra hardening, while [Formula: see text][Formula: see text]l does not show any change in the glass-like phase and monotonously decreases with a field increase in the paraelectric state. For complete understanding of the microscopic origin of the observed phenomena, a detailed study on the short- and long-range structures at the same condition is necessary.
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