Infrared ellipsometry study of the charge dynamics in 
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-terphenyl

He, Qi; Maršík, Přemysl; Mardelé, F. Le; Xu, Bing; Sharma, M.; Pinto, Nicola; Perali, Andrea; Nicola, Corrado Di; Pettinari, Cláudio; Baeriswyl, D.; Bernhard, C.

doi:10.1103/physrevb.107.094520

Phys. Rev. B

2023

DOI: 10.1103/physrevb.107.094520

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Infrared ellipsometry study of the charge dynamics in K3p -terphenyl

Qi He

Přemysl Maršík

F. Le Mardelé

et al.

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Orientation transitions and chiral assemblies of para-terphenyl molecules on Cd(0001)

Li,

Yang,

Wang

et al. 2024

The Journal of Chemical Physics

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The interplay between orientation transition and chiral self-assemblies of para-terphenyl (P3P) molecules on the Cd(0001) surface has been investigated using low temperature scanning tunneling microscopy and density functional theory calculations. Three distinct molecular orientations have been discerned from the self-assembled thin films of P3P. At the low coverage, flat-lying molecules appear in the homochiral domains with the incommensurate registry to the substrate. With the coverage increasing, the incoming molecules are incorporated into the first layer with edge-on orientation and form the self-assembled zigzag chains. The alternative arrangement of zigzag chains with opposite chirality leads to the formation of a c(4 × 2) superstructure, in which the tilted molecules exhibit orientational frustration and fuzzy noises. The analysis of the tunneling spectra reveals that the electronic structure of P3P layers is contingent upon the hybridization between the electronic states of P3P molecules and the Cd(0001) surface. These results provide important insights into the interplay between orientational transition and chiral assembly of P3P molecules on metal substrates.

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Orientation transitions and chiral assemblies of para-terphenyl molecules on Cd(0001)

Li,

Yang,

Wang

et al. 2024

The Journal of Chemical Physics

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show abstract

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Infrared ellipsometry study of the charge dynamics in K3p -terphenyl

Cited by 1 publication

References 72 publications

Orientation transitions and chiral assemblies of para-terphenyl molecules on Cd(0001)

Orientation transitions and chiral assemblies of para-terphenyl molecules on Cd(0001)

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