the terrestrial radiation with a temperature of ≈300 K at the Earth's surface is concentrated at wavelengths ranging from 2.5 to 50 µm. Meanwhile, the combined effects from all atmospheric components result in that the special atmospheric window between 8 and 13 µm that is highly transparent. Hence, most terrestrial areas can effectively radiate heat through the transparent atmospheric window to the cold universe to maintain a relatively stable temperature. To this end, radiative coolers should have high emissivity in the transparent atmospheric window (8-13 µm), which is transparent in this region and allows infrared (IR) light to pass through. In this regard, various materials and structures have been designed in the past few decades and have exhibited promising passive cooling performance at night. [8,9] However, during the daytime, the Sun heats the radiative coolers, which seriously compromises the cooling effect. To resolve this problem, the cooler should radiate more heat to the cold universe while reflecting sunlight to avoid solar heating. Fan and co-workers [10] first designed multilayer photonic materials and achieved daytime radiative cooling to a temperature below ambient conditions when subjected to direct sunlight. Since then, various materials have been demonstrated to realize subambient daytime radiative cooling and have shown great potential for practical applications. [11][12][13] Before some reviews have summarized these developments in radiative cooling, [14][15][16][17] but the limited net cooling power and instability of radiative cooling hinder its practical wide applications. In this review, by summarizing the state-of-the-art research and development in passive daytime radiative cooling (PDRC), we first propose three critical components for PDRC: 1) spectral design in the mid-IR range, 2) structure design for enhancing solar reflectance, and 3) thermal management. Second, we introduce various applications of PDRC, such as building cooling, solar cell cooling, water harvesting, clothing, and electricity generation (Figure 1). Finally, the remaining challenges and opportunities of PDRCs are also discussed.
Fundamental Mechanisms of PDRC
PDRC ConceptBased on Kirchhoff's law, an object with a temperature higher than 0 K continuously exchanges heat with other objects by absorbing Passive daytime radiative cooling (PDRC) is emerging as a promising cooling technology. Owing to the high, broadband solar reflectivity and high mid-infrared emissivity, daytime radiative cooling materials can achieve passive net cooling power under direct sunlight. The zero-energy-consumption characteristic enables PDRC to reduce negative environmental issues compared with conventional cooling systems. In this review, the development of advanced daytime radiative cooling designs is summarized, recent progress is highlighted, and potential correlated applications, such as building cooling, photovoltaic cooling, and electricity generation, are introduced. The remaining challenges and opportunities of PDRCs are also in...