Infrared Reflection Absorption Study for Carbon Monoxide Adsorption on Chromium Deposited Cu(100) Surfaces

Abstract

This study investigates carbon monoxide (CO) adsorption and desorption behaviors on 0.1-0.6-nm-thick Cr-deposited Cu(100) surfaces using infrared reflection absorption (IRRAS) and temperature-programmed desorption (TPD) spectroscopic methods. The low-energy electron diffraction (LEED) pattern for the 0.1-nm-thick Cr-deposited Cu(100) surface indicates that distorted bcc-Cr(110) grows on fcc-Cu(100). The CO exposure to a clean Cu(100) at 90 K produces a single and sharp IR absorption band at 2090 cm À1 that is attributable to adsorbed CO on the on-top site of the Cu atoms' on the surface. Two absorption bands are located at 2085 and 2105 cm À1 on the IRRAS spectrum for the COsaturated 0.1-nm-thick Cr/Cu(110) surface. The former might originate from linearly bonded CO on the uncovered Cu substrate surface. With increasing Cr thickness, the latter high-frequency band becomes prominent. For the 0.3-nm-thick Cr surface, the band at 2117 cm À1 dominates all spectra through CO exposure. The TPD spectra of the Cr-deposited Cu surfaces show two remarkable features at 220-250 and 320-390 K, which are ascribable respectively to Cu-CO and Cr-CO bonds. Lower desorption peaks shift to higher temperatures with increasing Cr thickness. Based on TPD and IRRAS results, adsorption-desorption behaviors of CO on the Cr-deposited Cu(100) surfaces are discussed herein.

Theoretical Investigation Of Coverage Effects Of CO Adsorption On Cu(100) Surface

“…However, the bifurcations may shed a light to a different phenomenon. Experimental works reported shoulders in the vibrational spectra that shift or diminish with the coverage [2,5,18,21,24,32]. Two explanations given for this phenomenon are i) the dipole effects, and ii) adsorption of CO on different sites.…”