1995
DOI: 10.1016/0009-2614(95)01160-2
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Infrared spectroscopic studies of photoinduced reactions of methyl radical in solid parahydrogen

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Cited by 28 publications
(30 citation statements)
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“…The experimental procedure is the same as in our previous work 7,8 and is elaborated in a review article. 3 Briefly, normal hydrogen gas was converted to p-H 2 which contained about 0.01% residual orthohydrogen.…”
Section: Methodsmentioning
confidence: 99%
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“…The experimental procedure is the same as in our previous work 7,8 and is elaborated in a review article. 3 Briefly, normal hydrogen gas was converted to p-H 2 which contained about 0.01% residual orthohydrogen.…”
Section: Methodsmentioning
confidence: 99%
“…3,7,8 In these studies, using a low pressure mercury lamp, however, we obtained methane and ethane, in addition to methyl radical. As for the mechanism of the formation of ethane, a consistent explanation was put forth by referring to the result of laser photolysis of methyl iodide in molecular cluster beams, which invokes the involvement of methyl iodide dimers.…”
Section: Introductionmentioning
confidence: 93%
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“…Several advantages of using solid parahydrogen (pH 2 [13]) as a matrix host have been extolled by collaborating groups in Kyoto and Chicago [4,7,8,11,12]. They note the spherical nature of J=0 pH 2 , which is preserved in SMH [1].…”
Section: Pacs Numbersmentioning
confidence: 99%
“…We recently reviewed the literature on MIS of trapped atomic impurities in SMH [3], as part of our work on condensed phase reactions of energetic species. We have begun to employ spectroscopic characterization of molecular impurities in SMH, a field showing considerable current activity [4][5][6][7][8][9][10][11][12]. However, certain difficulties in using the SMH as matrix hosts remain to be overcome.…”
Section: Pacs Numbersmentioning
confidence: 99%