A prototype monolithic 2 × 2 square pixel Al 0.2 Ga 0.8 As p + -i-n + mesa photodiode array (each photodiode of area 200 µm by 200 µm, with a 3 µm i layer) has been investigated for its utility as a detector for direct detection electron (βparticle) spectroscopy. Each photodiode was electrically characterised and its response to illumination from a 63 Ni radioisotope βparticle source was investigated at 20 °C. The percentage of electron energy absorbed in the active layer (i layer), E abs , of the photodiode and the spectrum expected to be detected, were calculated via Monte Carlo simulations. Comparisons between the simulated and detected 63 Ni βparticle spectra are presented and demonstrate uniformity in response across the two by two pixel array. The percentage of electron energy absorbed in the active layer of the detector was at a maximum of 0.53 ± 0.04 for electrons with an energy of 38 keV; the percentage of electron energy absorbed in the active layer of the detector reduced to 0.29 ± 0.02 at 66 keV.To increase the percentage of electron energy absorbed in the active layer of the detector at high energies, inactive Al absorption layers placed atop the detecting structure were investigated as part of the modelling work.These additional Al layers partially attenuated the βparticles' energy, thus reducing the incident particles' energy to values more readily detected by the relatively thin photodiode. Al layers of 20 µm, 100 µm, and 500 µm thickness were investigated and found, by modelling, to increase the percentage of electron energy absorbed