1991
DOI: 10.1007/bf00958554
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Inhibiting action of sulfur-containing hydroquinolines during polymerization of vinyl monomers

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“…
Many substances with a broad spectrum of biological action have been observed among substituted 4,4-dimethyl [1,2]dithiolo [3,4-c]quinoline-1-thiones, and these compounds furthermore exhibit antioxidant activity and also are radical polymerization regulators [1,2]. With the aim of obtaining novel polycondensed heterocyclic systems, we have continued work on further modification of these compounds.

We reported earlier [3] that acylation of 8-R-4,4-dimethyl-4,5-dihydro[1,2]dithiolo[3,4-c]quinoline-1thiones 1a-c by oxalyl chloride, as in the case of simple acyl chlorides [4], occurs exclusively at the nitrogen atom of the dihydroquinoline ring and is accompanied by spontaneous cyclization according to a Stolle reaction [5].

…”
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confidence: 99%
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“…
Many substances with a broad spectrum of biological action have been observed among substituted 4,4-dimethyl [1,2]dithiolo [3,4-c]quinoline-1-thiones, and these compounds furthermore exhibit antioxidant activity and also are radical polymerization regulators [1,2]. With the aim of obtaining novel polycondensed heterocyclic systems, we have continued work on further modification of these compounds.

We reported earlier [3] that acylation of 8-R-4,4-dimethyl-4,5-dihydro[1,2]dithiolo[3,4-c]quinoline-1thiones 1a-c by oxalyl chloride, as in the case of simple acyl chlorides [4], occurs exclusively at the nitrogen atom of the dihydroquinoline ring and is accompanied by spontaneous cyclization according to a Stolle reaction [5].

…”
mentioning
confidence: 99%
“…Many substances with a broad spectrum of biological action have been observed among substituted 4,4-dimethyl [1,2]dithiolo [3,4-c]quinoline-1-thiones, and these compounds furthermore exhibit antioxidant activity and also are radical polymerization regulators [1,2]. With the aim of obtaining novel polycondensed heterocyclic systems, we have continued work on further modification of these compounds.…”
mentioning
confidence: 99%
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