2017
DOI: 10.17675/2305-6894-2017-6-4-6
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Inhibition effect of 1,1´-(pyridine-2,6-dihylbis(methylene))bis(5- methyl-1-H-pyrazole-3-carboxylic acid) on the corrosion of mild steel in 1 M HCl. Part A: Experimental study

Abstract: The inhibitory effect of 1,1´-(pyridine-2,6-dihylbis(methylene))bis(5-methyl-1-H-pyrazole-3-carboxylic acid) (EM1) was estimated on the corrosion of mild steel in 1 M hydrochloric acid using weight loss, Electrochemical Impedance Spectroscopy (EIS) and Tafel polarization curves. Inhibition was found to increase with increasing concentration of inhibitor studied. The adsorption of inhibitor molecules on mild steel surface was found to be spontaneous and obeyed the Langmuir adsorption isotherm. Values of inhibit… Show more

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Cited by 3 publications
(2 citation statements)
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“…(8) is -19.513 kJ mol/L. The negative sign of 0 ads G  indicates that spontaneity of the adsorption process and the stability of the double layer adsorbed on the metal surface [27,28].…”
Section: Electrochemical Impedance Spectroscopy (Eis)mentioning
confidence: 99%
“…(8) is -19.513 kJ mol/L. The negative sign of 0 ads G  indicates that spontaneity of the adsorption process and the stability of the double layer adsorbed on the metal surface [27,28].…”
Section: Electrochemical Impedance Spectroscopy (Eis)mentioning
confidence: 99%
“…The polar functional groups along with the non-bonding electrons of heteroatoms and pi-electrons of the multiple bonds behave as adsorption centres during interactions between inhibitor and metal surface. The interactions of inhibitors with metal result into their adsorption on the surface which is behaves as barrier for corrosion process [21][22][23][24][25][26][27].…”
Section: Corrosion Monitoring Techniquesmentioning
confidence: 99%