Chemical inhibition
of asphaltene deposition is considered a cost-effective
way to prevent the harsh consequences of asphaltene instability in
the produced crude. Thus, a careful screening of asphaltene inhibitors
is crucial for an efficient prevention. However, the characteristics
of asphaltenes such as their acid–base properties will influence
the selection of an asphaltene inhibitor and the inhibition mechanism.
Therefore, improved knowledge on asphaltene acidic and basic fractions
is important. In this work, the separation of asphaltenes into acid,
base, neutral, and amphoteric fractions was performed. Among the existing
techniques to fractionate asphaltenes, the method of Ramljack was
adopted and applied on a light oil extracted asphaltene. However,
this oil was sampled from one of the wells in the Hassi Messaoud field
in Algeria that experienced a recurring deposition of asphaltenes.
The results of asphaltene fractionation reveal that the half composition
of this heavy part of crude oil is active functions gathered acid
and base components. However, the main contribution is reported to
the neutral fraction. The characterization results of infrared and
elementary analyses show that both active fractions are aromatic and
polar. Moreover, the acid fraction contains in its structure carboxylic
acids, phenols, sulfoxide groups, and aliphatic chains, while the
structure of the base fraction contains amines, sulfoxide groups,
and aliphatic chains.