Hydrogen peroxide, H2O2, is a promising and nontoxic oxidant. In recent years considerable attention has been paid to the development of hypergolic system compositions, because the use of them not only markedly simplifies the engine design and rocket system operation but also provides the possibility of their repeated use. Moreover, their high performance, high environmental compatibility and low toxicity make them highly preferable. The present review considers recent works on hypergolic systems involving hydrogen peroxide as the oxidizer and various green propellants of organic and inorganic nature with or without certain additives.