2023
DOI: 10.1002/ange.202304461
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Initiator‐Activation Strategy‐Enabled Organocatalyzed Reversible‐Deactivation Radical Polymerization Driven by Light

Abstract: Organocatalyzed reversible-deactivation radical polymerizations (RDRPs) are attractive for many applications. Here, we developed photoredox-mediated RDRP by activating (hetero)aryl sulfonyl chloride (ArSO 2 Cl) initiators with pyridines and designing a novel bis(phenothiazine)arene catalyst. The in situ formed sulfonyl pyridinium intermediates effectively promote controlled chain-growth from ArSO 2 Cl, enabling access to various well-defined polymers with high initiation efficiencies and controlled dispersitie… Show more

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