We have investigated rovibronic levels of the strongly mixed b 3 Π1 − c 3 Σ + 1 − B 1 Π1 states [the 2(1), 3(1), and 4(1) states in Hund's case (c) notation] of 85 Rb 133 Cs in the energy range of 13950−14200 cm −1 using short-range photoassociation (PA). For selected PA states, vibrational and rotational branching in the X 1 Σ + state have been investigated using resonance-enhanced multiphoton ionization and depletion spectroscopy. Efficient production of 85 Rb 133 Cs molecules in the rovibronic ground state X 1 Σ + (v = 0, J = 0), at up to ∼1×10 4 molecules/s, has been achieved.