Natural fiber‐reinforced composites have emerged as a promising alternative in various industries, including automotive, aerospace, construction, and civil engineering, owing to their eco‐friendly nature and favorable mechanical properties. However, challenges such as low thermal stability and high moisture absorption limit their widespread use. To overcome these limitations, surface modifications such as mercerization, benzoylation, silane treatment, and acetylation have been extensively explored. Hybrid composites (HCs), combining natural and synthetic fibers, offer a compelling solution by harnessing the unique properties of both materials. This review comprehensively examines the types of fibers and polymers utilized in HCs, along with various chemical treatments to enhance their properties. Additionally, a detailed analysis of different manufacturing processes for HCs is provided, including hand lay‐up, vacuum‐assisted resin transfer molding, autoclave molding, injection molding, and compression molding. Furthermore, this review highlights recent advancements in HCs and their applications. Significant outcomes include a deeper understanding of the synergistic effects between natural and synthetic fibers, improved mechanical and thermal properties, and enhanced applications in diverse industries. The potential of HCs as a sustainable and high‐performance material solution emphasizes the importance of ongoing research and innovation in this field to overcome existing challenges and unlock new possibilities for composite engineering.Highlights
Surface modifications such as mercerization, benzoylation, and silane treatment enhance the properties of natural fibers in composite materials.
Hybrid composites (HCs) offer unique advantages by combining natural and synthetic fibers, including improved thermal, mechanical, and damping properties.
Various chemical treatments and manufacturing processes contribute to enhancing the properties and applications of HCs.
Recent advancements in HCs have led to an improved understanding and utilization of composite engineering across multiple industries.
The review discusses challenges, opportunities, and future prospects for HCs, emphasizing the need for ongoing research and innovation in this field.