2005
DOI: 10.1179/003258905x37710
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Injection moulding of oxide reduced copper powders

Abstract: Fine oxide reduced copper powders of about 10 mm mean grain size are irregular in particle shape and high in oxygen content, which poses a difficulty in achieving good properties from injection moulding. Injection moulding was possible when a multicomponent binder with a large fraction of the backbone polymer was used. Injection moulded parts could be sintered to a density of about 95% theoretical, if reduction of the residual oxides in the powder was effectively carried out prior to closure of pores during si… Show more

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Cited by 12 publications
(8 citation statements)
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“…When compared to conventionally manufactured pure copper (8.9 g cm −3 ), this corresponds to 88.5 % or 93.3 %, respectively. While these two filaments reached a density comparable to state-of-the-art processes like metal injection molding (MIM) (about 95 % density [33]) or selective laser melting (about 95 % to 98 % density [34,35]), filaments F1 and F2 showed a significantly lower density after vacuum sintering (53.5 % for F1 and 63.4 % for F2). Only two filaments showed a significant improvement in the resulting density while using Ar during the thermal debinding and the forming gas mixture during sintering.…”
Section: Metal-fff On Specimen Scalementioning
confidence: 93%
“…When compared to conventionally manufactured pure copper (8.9 g cm −3 ), this corresponds to 88.5 % or 93.3 %, respectively. While these two filaments reached a density comparable to state-of-the-art processes like metal injection molding (MIM) (about 95 % density [33]) or selective laser melting (about 95 % to 98 % density [34,35]), filaments F1 and F2 showed a significantly lower density after vacuum sintering (53.5 % for F1 and 63.4 % for F2). Only two filaments showed a significant improvement in the resulting density while using Ar during the thermal debinding and the forming gas mixture during sintering.…”
Section: Metal-fff On Specimen Scalementioning
confidence: 93%
“…However, by mixing, cross contamination should be avoided throughout the molding and maintain the higher thermal conductivities. 21) The injection molding was carried out with three different injection parameters as indicated in Table 2. This results in different material properties, as will be discussed later.…”
Section: Moldingmentioning
confidence: 99%
“…The adding of reactive dopants, for example, Al, Cr, and Si, can easily enable getter oxygen control, but, degrading the conductivity. 21,22) The removal of oxygen before the last-step pore closure will lead to around a 92% density, typically requiring nitrogen sintering along with properly planned thermal cycles. 23,24) 2.5 Thermal conductivity, electrical conductivity and CTE measurement The thermal measurement evaluation was carried out using the metaproperty measurement capabilities LFA 447 Nano flash (Netzsch).…”
Section: Debinding and Sinteringmentioning
confidence: 99%
“…Essentially, the cross contamination should be avoided during whole feedstock preparation process; otherwise, several defects will show up in the final part, and it will affect thermal conductivity. 24) The injection molding was carried out as shown in Fig. 3 with two different injection parameters as indicated in Table 2.…”
Section: Moldingmentioning
confidence: 99%
“…In order to eliminate further issues associated with water vapor, the oxygen amount in the sintering environment should be decreased. 24,25) Elimination of oxygen in the sintering would enhance pore closing that leads to near up to 92% density of the final part. Therefore, it usually needs nitrogen sintering along with properly planned thermal cycles.…”
Section: Debinding and Sinteringmentioning
confidence: 99%