2006
DOI: 10.1080/00102200500292464
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Injection of Fluids Into Supercritical Environments

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Cited by 305 publications
(116 citation statements)
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“…Supercritical fluids are applied as solvents in food-and pharmaceutical processing [3,4] and as propellants [5,6]. Nonetheless, our understanding of these thermodynamic states is still limited: it has become clear that the notion of the supercritical state-space as a featureless domain has to be revised: Experiments show that in extension to the subcritical coexistence line (CL), there exists a supercritical crossover line across which fluid properties change continuously from a liquid-like to a gas-like state over a small temperature interval [7][8][9][10].…”
Section: Introductionmentioning
confidence: 99%
“…Supercritical fluids are applied as solvents in food-and pharmaceutical processing [3,4] and as propellants [5,6]. Nonetheless, our understanding of these thermodynamic states is still limited: it has become clear that the notion of the supercritical state-space as a featureless domain has to be revised: Experiments show that in extension to the subcritical coexistence line (CL), there exists a supercritical crossover line across which fluid properties change continuously from a liquid-like to a gas-like state over a small temperature interval [7][8][9][10].…”
Section: Introductionmentioning
confidence: 99%
“…However, only a few sets of quantitative experimental data have been made public compared with data on incompressible variable-density jets [7]. To the best of the authors£ knowledge, Raman-scattering-based density pro¦les of transcritical nitrogen jets are the only quantitative data that have been published [1,8]. These pro¦les showed that the spatial growth rate of transcritical jets agrees with those predicted by the theoretical equations and measurements for incompressible variable-density turbulent jets.…”
Section: Introductionmentioning
confidence: 63%
“…Cryogenic oxygen at an initially subcritical temperature is injected into an environment that exceeds the critical pressure and temperature (5.04 MPa and 154.6 K, respectively). The thermodynamic change from subcritical temperature to supercritical temperature under supercritical pressures is called ¤transcritical¥ [1]. The pseudocritical temperatures under transcritical conditions correspond to the boiling temperatures at subcritical pressures.…”
Section: Introductionmentioning
confidence: 99%
“…The experiments by Oschwald et al [5] show these di¨erences, perhaps, most clearly. In one of their experiments, liquid nitrogen was injected at subcritical temperature (T ≈ 110 K, whereas T c (N 2 ) = 126 K) into a chamber ¦lled with nitrogen at supercritical temperature (300 K), varying the chamber pressure from a sub-to supercritical value.…”
Section: Introductionmentioning
confidence: 97%