2021
DOI: 10.1002/ange.202111971
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Innenrücktitelbild: Topochemical Ene–Azide Cycloaddition Reaction (Angew. Chem. 47/2021)

Abstract: Topochemische Reaktionen sind kristallgittergesteuerte Reaktionen, die in Kristallen oder anderen sterisch starren Medien ablaufen. Bislang sind jedoch nur eine Handvoll topochemischer Reaktionen bekannt. In ihrem Forschungsartikel auf S. 25079 berichten K. M. Sureshan und R. Khazeber über eine neue topochemische Reaktion: die topochemische En‐Azid‐Cycloaddition, bei der ein proximal angeordnetes Azid und ein Alken eine Einkristall‐zu‐Einkristall‐Cycloaddition zu Triazolin durchlaufen.

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“…We have exploited the Topochemical Azide-Alkyne Cycloaddition (TAAC) reaction for the successful synthesis of many crystalline polymers, [37] including mimics of polysaccharides, [38,39] proteins, [40][41][42][43][44] and nucleic acids. [45] We recently introduced the Topochemical Ene-Azide Cycloaddition (TEAC) reaction, [46,47] which allows the synthesis of polymers whose backbone can be modified post-synthetically via the denitrogenation of the triazoline ring formed in the cycloaddition reaction. Additionally, as a new chiral center is generated in the ene-azide cycloaddition reaction, the TEAC reaction can be potentially regiospecific and stereospecific.…”
mentioning
confidence: 99%
“…We have exploited the Topochemical Azide-Alkyne Cycloaddition (TAAC) reaction for the successful synthesis of many crystalline polymers, [37] including mimics of polysaccharides, [38,39] proteins, [40][41][42][43][44] and nucleic acids. [45] We recently introduced the Topochemical Ene-Azide Cycloaddition (TEAC) reaction, [46,47] which allows the synthesis of polymers whose backbone can be modified post-synthetically via the denitrogenation of the triazoline ring formed in the cycloaddition reaction. Additionally, as a new chiral center is generated in the ene-azide cycloaddition reaction, the TEAC reaction can be potentially regiospecific and stereospecific.…”
mentioning
confidence: 99%