Black
body materials are promising candidates to meet future energy
demands, as they are able to harvest energy from the total bandwidth
of solar radiation. Here, we report on high-absorption near-blackbody-like
structures (>98% for a wide solar spectrum range from 220 to 2500
nm) consisting of a silica scaffold and Ag nanoparticles with a layer
thickness below 10 μm, fabricated using metastable atomic layer
deposition (MS-ALD). Several effects contribute collectively and in
a synergistic manner to the ultrahigh absorption, including the pronounced
heterogeneity of the nanoparticles in size and shape, particle plasmon
hybridization, and the trapping of omnidirectionally scattered light
in the 3D hierarchical hybrid structures. We propose that, in the
future, MS-ALD needs to be considered as a simple and promising method
to fabricate blackbody materials with excellent broadband absorption.