Organically crosslinked polymer systems have experienced considerable commercial success in shutting off undesirable water production. One of the systems most widely used to date employs acrylamide-containing polymers as base polymers and polyamines as crosslinkers. Its success can be attributed to 1) low viscosity in a noncrosslinked state, 2) versatility and stability over a wide temperature range, 3) rigid ("ringing") gel formation, and 4) deep matrix penetration.
The objective of the present study was to improve the current acrylamide- and amine-based polymer formulations by significantly reducing the polymer concentrations while retaining the gel performance. This was accomplished by the inclusion of organic activators that substantially increase the crosslinking reactivity of the polyamine, allowing reduction in the polymer loading necessary to achieve desired gel times at a specific temperature. The activator materials included alkanolamines and quaternary ammonium salts. An increase in base polymer molecular weight also allowed for significant reduction in base polymer concentrations (to ≤ 1%). While this results in a lower cost system, and is more environmentally acceptable, the change in the quality of the gel from a stiff to a highly deformable type can result in the decreased ability of the gel to resist pressure. Bimodal molecular weight distribution is presented as an alternative approach to decrease polymer loading. This technique consists of the addition of variable amounts of high-molecular-weight base polymer to a constant concentration of low-molecular-weight base polymer.
The newly developed formulations, in some cases, allowed for a reduction of up to 40% of base polymer concentration. Results from gel time measurements over a wide temperature range using different base polymers, crosslinker polymers, and potential activation mechanism(s) are discussed.