Inorganic and organometallic polymers– an overview

Sheats, John E.; Carraher, Charles E.; Jr., Charles Pittmann,; Zeidin, Martel

doi:10.1002/1521-3900(200007)156:1<79::aid-masy79>3.0.co;2-v

Cited by 3 publications

(1 citation statement)

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“…For instance, a sandwich complex, also known as metallocene, in which two π ‐bonded hydrocarbons or their derivative ligands lie on either side of a metal cation, is an attractive strategy for the introduction of metals into macromolecular frameworks. Since the first report on a sandwich complex‐containing macromolecule, polyferrocene, by Arimoto and Haven in 1955, interest in this class of polymers has continued to grow and the numerous published reviews on sandwich complex‐containing macromolecules attest to the importance of this class of organometallic macromolecules . Here, we highlight the tunability of the properties of sandwich complex‐containing macromolecules through synthetic exploitation of their well‐established chemistry.…”

Section: Introductionmentioning

confidence: 89%

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

Abd‐El‐Aziz

Agatemor

Etkin

2014

Macromol. Rapid Commun.

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Sandwich complexes feature unique properties as the physical and electronic properties of a hydrocarbon ligand or its derivative are integrated into the physical, electronic, magnetic, and optical properties of a metal. Incorporation of these complexes into macromolecules results in intriguing physical, electrical, and optical properties that were hitherto unknown in organic-based macromolecules. These properties are tunable through well-designed synthetic strategies. This review surveys many of the synthetic approaches that have resulted in tuning the properties of sandwich complex-containing macromolecules. While the past two decades have seen an ever-growing number of research publications in this field, gaps remain to be filled. Thus, we expect this review to stimulate research interest towards bridging these gaps, which include the insolubility of some of these macromolecules as well as expanding the scope of the sandwich complexes.

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Section: Introductionmentioning

confidence: 89%

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

Abd‐El‐Aziz

Agatemor

Etkin

2014

Macromol. Rapid Commun.

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The synthesis, characterization and polycondensation of metal‐containing diols: crystal structure of [(η⁵‐C₅H₅)(CO)₂Fe(CH₂)₃O‐{2,6‐(CH₂OH)₂‐4‐CH₃C₆H₂}]

Mapolie

Mavunkal

Moss

et al. 2002

Applied Organom Chemis

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The synthesis of two new transition‐metal‐containing polyesters is described. The precursors are bifunctional organometallic monomers that were synthesized using 2,6‐bis(hydroxymethyl)‐p‐cresol as the key reagent. This was achieved by simple coupling reactions between the appropriate organometallic alkyl halide and the cresol reagent. Polycondensation reactions were carried out with terephthaloyl chloride using ambient temperature solution techniques. The new low molecular weight oligomeric polyesters were characterized using Fourier transform infrared and 1HNMR spectroscopy, differential scanning calorimetry, thermogravimetric analysis and size‐exclusion chromatography analyses. Copyright © 2002 John Wiley & Sons, Ltd.

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Applications of Inorganic Polymeric Materials II: Polysilanes

Jamshidi

Rahimi

2006

Phosphorus, Sulfur, and Silicon and the Related Elements

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Inorganic and organometallic polymers– an overview

Cited by 3 publications

References 131 publications

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

The synthesis, characterization and polycondensation of metal‐containing diols: crystal structure of [(η⁵‐C₅H₅)(CO)₂Fe(CH₂)₃O‐{2,6‐(CH₂OH)₂‐4‐CH₃C₆H₂}]

Applications of Inorganic Polymeric Materials II: Polysilanes

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Inorganic and organometallic polymers– an overview

Cited by 3 publications

References 131 publications

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

Sandwich Complex‐Containing Macromolecules: Property Tunability Through Versatile Synthesis

The synthesis, characterization and polycondensation of metal‐containing diols: crystal structure of [(η5‐C5H5)(CO)2Fe(CH2)3O‐{2,6‐(CH2OH)2‐4‐CH3C6H2}]

Applications of Inorganic Polymeric Materials II: Polysilanes

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The synthesis, characterization and polycondensation of metal‐containing diols: crystal structure of [(η⁵‐C₅H₅)(CO)₂Fe(CH₂)₃O‐{2,6‐(CH₂OH)₂‐4‐CH₃C₆H₂}]